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Proline organocatalysis : ウィキペディア英語版 | Proline organocatalysis Proline organocatalysis is the use of proline as an organocatalyst in organic chemistry. Some proline-catalyzed Michael reactions initially provided poor enantioselectivity. Newer modifications, such as MacMillan’s catalyst and Jorgensen's catalysts, improved the stereocontrol.〔〔 == Background ==
Proline catalysis was initially reported by two groups at Schering AG and Hoffmann-La Roche.〔〔〔〔 Proline's chiral structure enables enantioselective synthesis, favoring a particular enantiomer or diastereomer.〔〔〔〔〔
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Proline organocatalysis」の詳細全文を読む
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